By K. Kuchitsu, E. Hirota, D. A. Ramsay, J. Vogt, N. Vogt (auth.), K. Kuchitsu, M. Tanimoto, N. Vogt (eds.)
Volume II/28 is a supplemented and revised version of the previous volumes II/7, II/15, II/21, II/23 and II/25, containing brand new info at the geometric parameters (internuclear distances, bond angles, dihedral angles of inner rotation etc.) of loose inorganic and natural polyatomic molecules. All experimental tools for the choice of quantitative structural info of loose molecules were thought of: microwave, infrared, Raman, digital and photoelectron spectroscopy in addition to electron diffraction. the information received through those equipment were seriously evaluated and compiled. they're offered individually for every molecule, including a computer-drawn schematic determine of the constitution and the unique literature.
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Extra resources for Inorganic Molecules
A 103 (1999) 1644. 3(13) The ED investigation was coupled with a quadrupole mass spectrometric experiment. The nozzle temperature was 360 K. a ) Estimated total errors. ) Effective dihedral angle of the four-membered ring between the Br(b)AlBr(b) planes due to the large-amplitude puckering vibration. : Chem. Phys. Lett. 257 (1996) 321. 1(31) θα No monomeric species of AlCl3 molecule were detected in the vapor. The effect of the largeamplitude ring puckering mode on the interatomic distances was handled by a dynamic model composed of a set of pseudoconformers.
Ag C∞v (effective symmetry class) (large-amplitude motion) Ar · AgBr The complex is linear and rather rigid in the ground vibrational state. The Ar…Ag stretching wavenumber is ca. 140 cm–1. a ) By a double substitution method. Uncertainties were not estimated in the original paper. : J. Chem. Phys. 112 (2000) 1321. Ag C∞v (effective symmetry class) (large-amplitude motion) Ar · AgCl The complex is linear and rather rigid in the ground vibrational state. The Ar…Ag stretching wavenumber is ca. 140 cm–1.
Chem. Phys. 2 (2000) 3943. 7 × 10–20 J rad–2, respectively. a ) Uncertainties were not estimated in the original paper. ) See figure for the definition. : Chem. Phys. Lett. 346 (2001) 103. Cu C∞v (effective symmetry class) (large-amplitude motion) Ar · CuBr The complex is linear and rather rigid in the ground vibrational state. The Ar…Cu stretching wavenumber is estimated to be ca. 200 cm–1. a ) Estimated standard errors. ) By a double substitution method. Uncertainties were not estimated in the original paper.