By Ferenc Joó (auth.)
Over the previous two decades aqueous organometallic catalysis has came across purposes in small- scale natural synthesis within the laboratory, in addition to within the business construction of chemical compounds with a mixed output just about 1000000 lots in step with 12 months. Aqueous/organic two-phase reactions let effortless product-catalyst separation and whole catalyst restoration which suggest transparent advantages not just in fiscal but in addition in environmental and eco-friendly chemistry contexts. rather than placing jointly a sequence of professional reports of specialised fields, this e-book makes an attempt to offer a complete but understandable description of a number of the catalytic adjustments in aqueous platforms as visible via an writer who has been engaged on aqueous organometallic catalysis for the reason that its foundation. Emphasis is wear the dialogue of transformations among similar non-aqueous and aqueous strategies a result of presence of water. The e-book could be of curiosity to specialists and scholars operating in catalysis, inorganic chemistry or natural synthesis, and will function a foundation for complicated courses.
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Additional info for Aqueous Organometallic Catalysis
Non-phosphine type ligands are studied time by time with the aim to obtain water-soluble transition metal complexes with catalytic properties. g. oxidations) these catalysts cannot cope with tertiary phosphines - with the ligands on Figure 20 this has been found once again. 9 39 SOLUBILITIES OF TERTIARY PHOSPHINES AND THEIR COMPLEXES IN WATER Water-soluble phosphines most often used to be prepared for the purposes of aqueous organometallic chemistry and catalysis. e. low) concentrations and whether they stay in the aqueous phase or tend to distribute between the aqueous and organic phases.
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Malström, C. Andersson, J. Mol. Catal. A. 2000, 157, 79 This Page Intentionally Left Blank Chapter 3 Hydrogenation Hydrogenation is one of the most intensively studied fields of metal complex catalyzed homogeneous transformations. There are several reasons for such a strong interest in this reaction. First of all, there are numerous important compounds which can be produced through hydrogenation, such as pharmaceuticals, herbicides, flavors, fragrances, etc [1-3]. Activation of is involved in other important industrial processes, such as hydroformylation, therefore the mechanistic conclusions drawn from hydrogenation studies can be relevant in those fields, as well.